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Riemann's green is a green pigment ZnO.CoO, which is obtained by heating a mixture of zinc oxide and cobalt nitrate or by the reaction of cobalt nitrate with either or zinc sulphate.
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At dawn and dusk, large amount of blue and violet light(shorter wavelength) has been scattered so, the light that is recieved by an observer is mostly of a longer wavelength and therefore appears to be red.
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