No, if three vectors do not lie in a plane, they cannot give zero resultant.

Explanation:

Let A, B and C be three vectors. If they give zero resultant, then

     A+B+C=0

or, A= -(B+C)

Hence, they will produce zero resultant, if A is equal to negative of vector (B+C). The vector (B+C) lies in the plane of B and C. Hence, A will be equal to negative of (B+C) if A, B and C all lie in a plane.

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In benzene molecule, carbon and carbon bond can't have polarity because there is not any electronegativity difference and the carbon hydrogen is also not much polar because the electronegativity difference is almost zero and also the small pull due to small difference in Electronegativity is balanced due to even pull from all directions.

In chlorobenzene the electronegativity difference between carbon and chlorine is very high so, it is polar.

(to compare polarity first check electronegativity...