It is theoretically possible for a substance to have a negative value of cubical expansivity, which means that the substance would contract rather than expand when the temperature increases. However, it is very rare for a substance to have a negative value of cubical expansivity over a significant range of temperatures.

One example of a substance that has a negative value of cubical expansivity over a limited range of temperatures is water. Water has a positive value of cubical expansivity at...

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zinc will react with sulphuric acid forming zinc sulphate dissolved in solution and releasing hydrogen gas.
Zn + conc. 2 H2SO4 ZnSO4 + SO2 + 2 H2O