II)Cr2+ is reducing agent as its configuration changes from d4 to d3, when it is oxidized to Cr3+ .The d3 configuration have a half-filled t2g level which is very stable. On the other hand, the reduction of Mn3+ to Mn2+ results in the half-filled (d5) configuration which has extra stability hence Mn3+ acts as oxidizing agent.
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Riemann's green is a green pigment ZnO.CoO, which is obtained by heating a mixture of zinc oxide and cobalt nitrate or by the reaction of cobalt nitrate with either or zinc sulphate.
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