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In benzene molecule, carbon and carbon bond can't have polarity because there is not any electronegativity difference and the carbon hydrogen is also not much polar because the electronegativity difference is almost zero and also the small pull due to small difference in Electronegativity is balanced due to even pull from all directions.
In chlorobenzene the electronegativity difference between carbon and chlorine is very high so, it is polar.
(to compare polarity first check electronegativity...
Sigma bond is stronger than Pi bond because of the following reasons:
- The extent of overlapping in Sigma bond is greater than in Pi bond.
- The electron density in intermolecular axis is more in Sigma bond than in Pi bond.
- There is free rotation of atom about Sigma bond but not about Pi bond.
Great my son!
You've been truly inspiration, dai! Congratulations to you and all of us.